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UNK35.TXT
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1993-02-13
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4KB
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202 lines
The liquid was insoluble in all the usual reagents.
1348
Typical of a saturated or aromatic hydrocarbon or a halogenated derivative.
Solvent is deuterochloroform.
µττττττµµµµµττττµτττττττττττΦττττΦµτΦΦΦΦΦΦΦΦΦΦΦΦτΦΦΦτµττΦΦΦΦΦΦτττµτΦΦΦΦΦΦΦτµµτΦΦΦΦΦτττττΦΦΦτττΣΓσττττττττµµµττττΦττττΦΦΦττττττττττττττµτΦτττττττττΦΦττττττττττττΦτµτττµτττττττττµµµµµττττττττττµττττµµµτµττττµµττµµµµµττττµµµµµτττµσσµµµµµµµµµµµµττττµµµµµµµµµµ
τµµµµµσσµττττµµµτµµµµµµµσµµµµµµσµßµσσσµµµσσµµσµµσΣσµµπ▐╪▐πσ▄╥═▄▐ΓΣß╤╟╙█ßΣΣ▀▄╓▄ßΣΣΣΣΣΣπΣµσσσσµσσσΣπσµµµσσµµµµµµσµσσσµσσσσσσσσΣΣσσµσσσσσµµµσσσσσσΣσµµµσσσΣΣΣσσσΣσσµσσΣπΣσΣπΣΣππΓπσσΣππΓΓπΣΣΣΣΓπΓσσσσσσσσσσµσσσσσσΣΣππα▐▐▐▀π▐▄╨╟╩╫▌▐┘╞S 4sÉqÉ╚╞üÇc\î┤╞╘▐█▌αΓΓΓΓΓßπ
πππΣΣΓΓΓααßπΣΣπß▀▌α╪┬¢ò╖┼╥▌╝¢üü£¡╕╔╪▐╪╥─╜╞╨┌ßπππΓΓΓππΣΣΣΓπΣΣΣΣΣπΣΣΣΣπΣπΣΣπΣΣππΣπππΣΣΣΓΓΓπππΣΣΣΣΣΣ╓╙╧╪▀ßßΓππΓαßΓßππσπè╗!┬ %╙z#
132023303334383941424344454648495154
The unknown is aliphatic (9 H's or multiple) with a strong deshielding group.
#
dummy ms
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Bromine was found to be present.
21253135394142434948
Absent are sulfur, nitrogen and the other halogens.
The liquid burnt with a clear flame.
#
The compound is aliphatic and saturated.
Below room temperature.
#
True for all liquids.
Liquid film
))('%&&&%$$#$$####"#"""""""####"""!"##"""#####$%&&'''''&''&%$%%%%&%%&''((()*,--,,+***,-./..03Çä┘Φα┬├╦╚┤½╖▓ƒçw~dJ?=50,*+.0350-+*)'&&&''&&&(('%%$&&&&&&&&&&&&(&&&&'$#$$%$%%$&&%$##$##""!!!!!! ! !!"#""""#######$$$$$###"""!""##$$$####$$$$####$$$%%&&&&'(),*)***
)))(((((('(((()**********++,-//246:>BSkuÜ╢╬╬╚├┬ªƒ|hZUPMWp¿╡¥âeOEC@<9;JYRKXà弪üeQGBCL^på╖▐α╖ûcOIEEPv₧╟½£íäk[qcSNLE:233469LclTC:DN\eÇÿëa_WZuûù~nI50+)'''&&%%%#$'+6~íé^RrZBFlƒ┤ûxN70.+)))**)('&(*(**)*,,*,,2:COké~p[JCMfcO@658Irò½èiS=<>NhrZIHMZWOQS_kuw|or
1419222427294231531320233033343839414243444546484951542850
The compound looks like a saturated aliphatic hydrocarbon.
90-91 degrees.
#
Fairly volatile; this must be a low molecular weight compound.
Optically inactive.
#
The unknown is not chiral.
1.256
#
Quite high for an organic compound; this suggests that a halogen is present.
1.437
#
A typical value.
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dummy cmr
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No precipitate was formed.
2227282950
This compound is not an aldehyde or a ketone.
No positive result.
3344454651
The compound is not an alcohol or phenol (ester, ketone etc. unlikely as well).
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No reaction was observed.
14
The unknown is not an ester.
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A precipitate formed after heating for five minutes.
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A reaction like this is typical of a secondary bromo-compound.
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No positive result.
3344454651
Absent are groups containing OH (alcohol or phenol) or NH (prim. or sec. amine).
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No reaction was observed.
#
This is not an unsaturated compound.
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No colour change was observed.
232850
The unknown is not a carbohydrate.
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No reaction took place.
#
Double or triple bonds between carbons are absent in this compound.
No reaction took place.
#
The unknown is not an ether.
No colour change was observed.
#
This compound is not a phenol.
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A precipitate was formed on heating.
#
This result suggests a bromo- or perhaps chloro-alkane.
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No reaction could be seen and the unknown did not dissolve.
#
The unknown is a saturated hydrocarbon (or a halogen derivative of one).
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No reaction was noted.
#
The unknown is not unsaturated nor is it a phenol.
No reaction took place.
#
Functional groups like esters, ketals, amides and nitriles are not present.
No positive result.
3344454651
The compound is not an alcohol, phenol, prim. amine or sec. amine.
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colourless liquid
010509
2640
6299
Solid m.p. 163-166 degrees.
Crystals m.p. 105 to 108 degees.
2
⌐╡⌐¥ó╜t╣╛=å╝½«║╢b
꥿┬»╡oó╟qà╕í
liquid brominated hydrocarbon
2
isobutyl bromide
sec-butyl bromide